Enhancing Solar Organic Rankine Cycle Performance with Refrigerant Mixtures

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Abstract

In recent issues in power generation emphasis the earnest requirement for a sustainable way to deal with help the flow power framework, increment its current limit, and similarly essential, advantage the earth by diminishing the need to construct more power plants and use naturally well-disposed synthetic compounds and warmth recuperation innovation, for example, Organic Rankine Cycle.

The main goal of this work is to improve the ORC execution and employ the distinctive refrigerant blend as a working liquid for Solar Organic Rankine Cycle, in fact the alternative of running fluid and working condition has good effect on nature.

The vitality and exergy investigation have been exhibited for practices of various refrigerant blend in Solar Organic Rankine Cycle and contrasted with other working fluids. The Organic effectiveness of refrigerant blend R245fa/R227ea is 4% more contrasted with unadulterated liquid R227ea at turbine outlet temperature of 353K.The Volume development proportion looking at refrigerant blend is decreased by 25.4% and 30% contrast with unadulterated refrigerant R227ea and R245fa.

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Introduction

Rankine Cycle plant are naturally poor entertainers. For instance, the biggest and unassuming present-day coal terminated Rankine cycle is commonly close to 35 percent productive. That is of the absolute vitality in the fuel that is scorched, just 35 percent of it is changed over to electricity. The 65 percent vitality misfortune is because of a large group of reasons. Around 15 percent vitality misfortune is because of dampness in the fuel, heat radiation from the heater dividers, low temperature pipe gas from the heater and helper influence.

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The Rankine 'cycle misfortunes' represent the rest of the 50 percent. This is fundamentally the vitality that is still in the steam at the turbine exhaust. In spite of the fact that this steam has a gigantic measure of vitality must, along these lines be discarded to the warmth sink just to gather the steam to water so it tends to be siphoned back to the evaporator. A brisk survey of thermodynamics will indicate why these cycle misfortunes are so huge.

In spite of the fact that Rankine Cycle is chosen as the power cycle however there are various issues which exist in traditional Rankine Cycle

A Rankine cycle uses the water as working fluid and it doesn't allow productive recuperation of waste warmth beneath 370°C.

One of the crucial issues of water is ought to be superheated in the Rankine Cycle. The superheating is imperative to ensure the idea of submerged water after the development in the turbine is dry.

The nature of submerged water should not be underneath 0.88. Right when the quality is lower, dimension of vapor will be higher and deterioration in turbine front line will be at a higher rate.

Due to low develop temperature, low weight, high unequivocal volume, tremendous turbine estimation required.

High weight drops to transform into a high enthalpy drop thusly exorbitant multi sort out turbines required.

Another issue for steam warm plant is the need to make a vacuum in the condenser. The temperature of a condenser is set by the temperature of the cooling liquid. It is exorbitant and difficult to keep up the vacuum in condenser as it is tremendous.

Solar Organic Rankine Cycle

  1. The Organic running liquid is pumped from low weight to high weight by isentropic pressure process.
  2. The high-weight working liquid enter in to the Flat plate gatherer (Boiler)where it is warmed steady weight by an outside sunlight-based radiation to turn into a superheated vapor.
  3. The too warmed vapor grows isentropically through turbine which is coupled to generator to deliver control yield.
  4. The vapor enters a condenser where it is cooled at consistent strain to turn into a soaked fluid, this fluid reappears the pump and cycle rehashes.

The present literature survey has been done to have knowledge of available in different application of waste heat recovery on low temperature Organic Rankine cycle and also discussed the theoretical investigations, thermodynamic analysis, experimental analysis, renewable energy and comparison Organic Rankine cycle and Rankine cycle.

HUNG.T.C etal [1] Examine Parametrically and analyzed the productivity of ORCs utilizing cryogens, for example, benzene, ammonia, R11, R12, R134a and R113 as working liquid and contrasted and water as reference. These effects of working liquids rely on the slant of the are immersion vapor bends on T-S chart. Isentropic liquids are the most appropriate for recouping low-temperature squander heat. When liquid was chosen, variety of framework effectiveness with turbine bay temperature and weight, at Specified Operating condition Temperature of condenser Tc=293K and Condenser outlet weight P3=2.5Mpa among the fluid inspected, benzene was to give most raised most astounding productivity pursued successively by R113, R11, R12, R134a and ammonia.

SanjayanVelauthametal[2] examine the practicality of an ORC driven by Solar thermal energy as a sustainable power source choice for little and medium measured business utilization, power generation under 10MW. The solar thermal cycle circulates heat move liquid in the cycle and bridle thermal energy from the sun and exchange it to the natural compound in the ORC by means of a heat exchanger R123 and iso-butane are chosen as working liquid ,among R123 gives a higher warm proficiency contrasted with iso-butane, R123 productivity ranges from 22 to 26% while iso-butane ranges from 17 to 19%.

LouayChamra.M etal[3] have examined the regenerative Rankine cycles 'ORC' using dry normal fluids, to convert low grade heat sources into useful energy. The working liquids decided for this examination are R113, R245ca, R123, and iso-butane, with breaking points reaching out from −12 °C to 48 ° C. Regenerative ORC is broke down and contrasted and the fundamental ORC so as to decide the best thermal efficiency with least irreversibility

Rayegan .R etal[4] had build up a method to analyze the efficiency enhancement of collector efficiency of working liquids when they are utilized in SORC and compare the results at same working conditions.

Zaho .L etal[5].proposed an exploratory framework is structured, developed and tried for low-temperature solar Rankine framework using R245fa as the working liquid. Both the emptied sunlight-based authorities and the level plate sun powered gatherers are utilized in the trial framework, in the meantime, a moving cylinder R245fa expander is likewise mounted in the framework.

Bertrand F etal[6] have completed an audit on Low-grade heat transformation into power utilizing natural Rankine cycles for different applications. This paper presents existing applications and researches their improvement of geothermal and matched biomass CHP to Provide the enthusiasm to recuperate squander heat dismissed by warm gadgets and mechanical procedures proceed to develop, and positive administrative conditions are received, squander heat recuperation natural Rankine cycle frameworks soon will encounter a quick development.

Roy.J.P etal[7] have investigation of non-regenerative Organic Rankine Cycle (ORC), in view of the parametric advancement, utilizing R-12, R-123, R-134a and R-717 as working liquids superheated at constant pressure. The determined outcomes uncover that R-123 produces the most extreme efficiencies and turbine work yield with least irreversibility for utilized consistent just as factor heat source temperature conditions. Subsequently, choice of a non-regenerative ORC amid superheating utilizing R-123 as working liquid gives off an impression of being a decision framework for changing over second-rate heat to power.

By Studying through all the journals in the area of natural Rankine cycle to upgrade the conduct of Solar Organic Rankine Cycle utilizing distinctive refrigerant blends and effect on the ORC execution. Vitality and Exergy examinations were connected to all the more likely comprehend the advantages of utilizing refrigerant blends between a similar temperature limit. I deduced that embracing Refrigerant blends in Solar natural Rankine cycle expands the waste heat recovery and produce control from low and medium temperature squander heat. Contrast with the unadulterated refrigerant as working liquid.

Selection of Working Fluids

Types of Working Fluids

Depending on inclination of Saturation vapor curve on a T–s diagram ds/dT. The sort of working liquid can be grouped by the estimation of ds/dT, i.e. ds/dT> 0 a dry fluid (e.g. pentane), ds/dT = 0 an isentropic fluid (e.g. R11), and ds/dT< 0 a wet fluid (example water) demonstrates the three kinds of liquids in a T–s diagram.

Isentropic or dry fluids may be proposed for an ORC to avoid liquid bead that strikes to the turbine blades amid the development and to prevent erosion of turbine blades

Thermodynamic Properties of Working Fluid

A Working liquid determination must not just have the necessary thermo-physical that coordinate the application but also possess adequate chemical stability in the covet temperature range. The liquid selection framework proficiency, working conditions, natural effect and economic viability.

For Simulating the Solar Organic Rankine Cycle the thermo physical properties of the working liquid of are R245fa-R227ea are considered. The properties of these liquids are talked about as underneath.

R245fa is presently utilized and considered as option in contrast to the CFCs R-11 and R-114 in the chillers and ORC applications.

This is because of high warmth exchange proportion between the warm vitality and dynamic vitality at the turbine side just as weight proportion.

R245fa-R227ea Properties

The properties of R245fa-R227ea are referred from models or from some software’s like REFPROP and MAT LAB and so on.

Refrigerant Properties
Refrigerant Molecular Weight (g/mol) Boiling Point (°C) Critical Pressure (kPa) Critical Temperature (°C) ASHRAE 34 Safety Group ODP GWP
R227ea 170.03 -16.42 2990 102.75 A1 3500
R245fa 134.02 15.14 3.65 154.01 B1 950

Table 3.1. Thermo physical properties of R245fa and R227ea

Simulation

The engineering calculation and simulation of the Solar Organic Rankine Cycle system requires the availability of simple and efficient mathematical methods for the determination of thermo physical property values of the operating fluid (mixture).Values of the thermo -physical property are necessary both at the key points in the cycle and along the process taking in the various components.

Assumption of ORC

  • The ORC depends on Unit mass working liquid.
  • The composition of the refrigerant Mixture doesn’t change in each process of the cycle
  • Temperature skimming of the working liquid disperses directly along heat exchanger and solar collector.
  • The inward protections in solar collector are unimportant and the condensation and dissipation pressures of working liquids keep consistent.

Operating Conditions

Refrigerant Mixture R227ea/R245fa [0.2 /0.8] by Mass Fraction

Condenser inlet temperature t1 =25 o C

Condenser Pressure p1 = p6 =p61= p7

Evaporator Pressure p2 = p3 = p4 = p5

Saturated Turbine Inlet temperature t4 = 80 o C

Superheated Turbine Inlet temperature t5 = 85 o C Turbine Efficiency = (h5 -h6 )/(h5 - h61 )= 0.8

Solar collector heat input QE = h5 - h2kW

Expansion work output W S = h5 -h6kW

Condenser heat rejection QC = h6 - h1 kW

Pump work input W P = h2 - h1 kW

Net power output W N = W S -W PkW

Volume expansion ratio = v6 /v5

Solar Organic Rankine cycle efficiency η R =W N / QE = W S -W P / QE

Second Law Efficiency η II = (WN ) /(QE* (1-(T1/T4))

Results and Discussions

In a simulation of the ORC with the refrigerant blend R227ea/R245fa [0.2/0.8] by mass part as working liquid between Condenser outlet temperature 25o C and Turbine channel temperature 80oC, isentropic effectiveness of turbine is 0.8%, considering for unit mass stream rate of working liquid. A parametric examination of the cycle, portrayed beneath demonstrates that the cycle conditions can be enhanced inside the scope of low temperature sunlight-based authorities for amplifying by and large effectiveness. The SORC can be improved to give greatest power produced and most extreme effectiveness for the refrigerant blend.

Effect of Working Fluids on Orc Efficiency

From the figure 5.1 observed that by increasing Turbine inlet temperature SORC efficiency for refrigerant mixture R227ea/R245fa [0.2/0.8] by mass fraction is greater by 4% compare to pure working fluid R227ea at turbine inlet temperature of 358 K ,This is mainly due to the lower boiling temperature and higher latent heat of evaporation compared to refrigerants .The SORC efficiency for Pure Refrigerant R245fa is greater compare to both Refrigerant mixture and Pure R227ea as turbine inlet temperature increases.

Effect of Net Power Output

From the figure 5.2 observed that by increasing Turbine inlet temperature the net power produce by the refrigerant mixture R245fa/R227ea is greater compare to pure refrigerant R227ea, this is because of increment in work delivered by the refrigerant blend at same warmth source.

Effect of Solar Collector Heat Input

From the figure 5.3 observed that by increasing Turbine inlet temperature The Solar collector heat input produce by the refrigerant mixture R245fa/R227ea is greater compare to pure refrigerant R227ea, by using Refrigerant mixture as working liquid in solar Organic Rankine cycle and it is better collector efficiency at same temperature ranges

Effect of Volume Expansion Ratio

From the figure 5.4 observed that by increasing Turbine inlet temperature. Volume expansion ratio is defined as ratio flow rate of at turbine outlet to flow rate at turbine inlet. For refrigerant mixture R245fa/R227ea the Volume Expansion ratio is less compare to pure refrigerant R227ea & R245fa, by comparing refrigerant mixture volume expansion ratio is reduced by 25.4% & 30% compare to pure refrigerant R227ea and R245fa. This implies that by using refrigerant mixture reduce smaller dimension and less expensive of expander that reduce cost of the system.

Effect of Second Law Efficiency

From the figure 5.5 observed that by increasing Turbine inlet temperature The Second law efficiency can be decreased by utilizing refrigerant blend compare to pure refrigerants, these is due to minimizing the system irreversibility which could be utilized to mismatch of temperature profile between heat transfer fluid and evaporating or condensing working fluid blends.

Effect of Working Fluids on Orc Efficiency vs Condenser Outlet Temperature

From the figure 5.6 observed that by increasing Condenser outlet temperature The Solar organic Rankine efficiency is decreasing linearly for both refrigerants’ mixtures and for pure refrigerants.

Effect of Second Law Efficiency

From the figure 5.7 observed that by increasing the Condenser outlet temperature Second law efficiency decreasing linearly for both refrigerants’ mixtures and for pure refrigerants.

Table 5.1 Performance comparison between Refrigerant Mixture and Pure Refrigerant

Refrigerants Properties
Refrigerants R227ea R245fa R227ea/R245fa[0.2/0.8] by mass Fraction
Evaporation bubble point temperature t3 (°C) 80 80 74.78
Evaporation dew point temperature t4 (°C) 80 80 80
Evaporation temperature glide t4 - t3 (°C) 5.21
Evaporation Pressure p3 (Kpa) 1860.2 788.1 899.3
Condensation bubble point temperature t1 (°C) 25 25 25
Condensation dew point temperature t7 (°C) 25 25 32.28
Condensation temperature glide t7 - t1 (°C) 7.2
Condensation Pressure p1 (Kpa) 455.17 149.43 223.4
Pump work input W P = h2 – h1 (kJ/kg) 1.012 0.47 0.5
Expansion work output W t = h5 - h6 (kJ/kg) 14.69 25.12 21.78
Net power output W N = W t - W P (kJ/kg) 13.68 24.64 21.28
Solar collector heat input QE = h5 - h2 (kJ/kg) 145.6 236.15 217.9
SORC Efficiency 9.39 10.43 9.78
Second law Efficiency 60.2 66 57.5
Turbine Expansion ratio 5.24 5.44 4.18

Conclusion

The Refrigerant mix have variable temperature amid the stage change process which could be used to decrease the puzzle of temperature profile between warmth exchange liquid and the scattering or consolidating working liquid mix.

The Organic proficiency of refrigerant blend R245fa/R227ea is 4% more appeared with pure fluid R227ea at turbine outlet temperature of 353K.

The Volume expansion proportion seeing refrigerant blend is diminished by 25.4% and 30% diverge from unadulterated refrigerant R227ea and R245fa. This deduces more diminutive estimation and progressively moderate of expander that lessen cost of the structure.

References

  1. T.C. Hung ,T.Y.Shai,S.K.Wang , “A Review of Organic Rankine Cycle for the Recovery of Low-Grade Waste Heat ”, Energy , Vol 22 ,1997,pp661-667.
  2. Sanjayanvelautham, “solar thermal organic Rankine cycle as a Renewable energy option”, Vol 20,2005,pp68-77.
  3. L.M. Chamra,P. J. Mago ,,C Somayaji , “Performance analysis of different working fluids for use in Organic Rankine cycles ”,Power and Energy, Vol 221 Pat A,2007,pp543-549.
  4. R.Rayegan,Y.X Tao , “A procedure to select working fluids for solar ORC’' ,Renewable energy ,Vol 36 ,2011, pg 659-670.
  5. L. Zhao, X D Wang, JL.Wang , “Performance evaluation of a low temperature solar organic Rankine cycle system utilizing R245fa “,Solar Energy ,Vol 84 2010,pp 353-64.
  6. Bertrand F. Tchanche , Gr. Lambrinos , “A. Frangoudakis , G. Papadakis ,“Low-grade heat conversion into power using organic Rankine cycles – A review of various applications”, Renewable and Sustainable Energy Reviews Vol15, 2011, pp. 3963– 3979
  7. J.P. Roy, M.K. Mishra , AshokMisra ,“Parametric optimization and performance analysis of a waste heat recovery system using Organic Rankine Cycle” , Energy, Vol 35,2010 , pp5049-5062.
  8. M.Lokanath and B.Balachandra, “simulation of solar organic rankine cycle using refrigerant mixtures as working fluid”.pp51-64.
Updated: Feb 19, 2024
Cite this page

Enhancing Solar Organic Rankine Cycle Performance with Refrigerant Mixtures. (2024, Feb 19). Retrieved from https://studymoose.com/document/enhancing-solar-organic-rankine-cycle-performance-with-refrigerant-mixtures

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