Alkali Metal Reactivity: Water, Chlorine, Oxygen, and Flame Tests

Categories: Chemistry

Element

Observation

pH indicator

Lithium

  • Move slowly on the surface of the water.

  • Emitted a negligible amount of white smoke

  • The reaction produced a colourless solution.

10

Sodium

  • Move moderately on the surface of the water with ‘hiss’ sound.

  • It burnt with yellow in colour.

  • Emitted white smoke

  • The reaction produced colourless solution

11

Potassium

  • Move enthusiastically on the surface of the water with ‘hiss’ and ‘pop’ sound

  • It burnt with red in colour in colour.

  • Emitted large amount of white smoke.

  • The reaction produced colourless solution.

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Experiment 2: Reactivity with chlorine.

Alkali Metal

Observation

Lithium

  • Burnt slowly with the red flame

  • Very heavy black soot are produced

  • A white solid is produced

Sodium

  • Moderate time to burn out with the yellow flame

  • Heavy black soot are produced

  • A white solid is produced

Potassium

  • Take short time to burn out with purple flame

  • White and black soot are produced

  • A white solid is produced

Experiment 3: Reactivity with oxygen

Element

Observation

pH indicator

Lithium

  • Burn slowly with the red flame

    • Emitted white smoke and the element changed its colour from grey to white in colour eventually.

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    • When the white solid is mixed up with water, it’s produced colourless solution.

8

Sodium

  • Burnt moderately with the yellow flame.

  • Emitted small amount of white smoke and the element changed its colour from white to black in colour.

  • When the white solid is mixed up with water, it’s produced colourless solution.

11

Potassium

  • Burnt robustly until the element become slightly red flame in colour

  • Emitted big amount of white smoke and the element changed from white to black colour

  • When the white solid is mixed up with water, it’s produced colourless solution.

14

Experiment 4: Flame tests

Metal chloride + HCl

Observation

Lithium Chloride (LiCl)

  • Change the mix solution to green-yellowish

  • Produced red flame

Sodium Chloride (NaCl)

  • Change the mix solution to yellowish

  • Produced violet flame

Potassium Chloride (KCl)

  • Change the mix solution to green-yellowish

  • Produced yellow flame

Experiment 1: Water Reactivity

Alkali metals exhibit a reaction with water, generating alkali solutions and liberating hydrogen gas. The chemical equations for this reaction are:

2Li(s)+2H2​O(aq)→2LiOH(aq)+H2​(g)

2Na(s)+2H2​O(aq)→2NaOH(aq)+H2​(g)

2K(s)+2H2​O(aq)→2KOH(aq)+H2​(g)

Observations show that as we move down the alkali metal group, reactivity increases. Testing LiOH, NaOH, and KOH with a pH indicator yields results above 7, indicating alkaline characteristics.

Experiment 2: Chlorine Reactivity

Alkali metals (Li, Na, K) react with chlorine gas, forming metal chlorides. The chemical equations are:

2Li(s)+Cl2​(g)→2LiCl(s)

2Na(s)+Cl2​(g)→2NaCl(s)

2K(s)+Cl2​(g)→2KCl(s)

Scientifically, in this reaction, alkali metals donate one electron to chlorine atoms to achieve inert noble gas configurations.

Experiment 3: Oxygen Reactivity

Alkali metals (Li, Na, K) react with oxygen to produce white-colored metal oxides. The chemical equations are:

4Li(s)+O2​(g)→2Li2​O(s)

4Na(s)+O2​(g)→2Na2​O(s)

4K(s)+O2​(g)→2K2​O(s)

Observations suggest that reactivity increases down the alkali metal group. These metal oxides dissolve in water to form metal hydroxide solutions with pH readings above 7. The chemical equations are:

Li2​O(s)+H2​O→2LiOH(aq)

Na2​O(s)+H2​O→2NaOH(aq)

K2​O(s)+H2​O→2KOH(aq)

Experiment 4: Flame Test

Alkali metals exhibit distinct flame colors as follows:

  • Lithium: Red
  • Sodium: Yellow
  • Potassium: Blue

Scientifically, when alkali metals are introduced into a flame, they emit characteristic colors. This phenomenon occurs as alkali metal ions are reduced to gaseous metal atoms. These atoms absorb sufficient energy from the high-temperature flame, causing electrons in the valence electron shell to become excited to higher energy levels. As these electrons return to their ground state, they release energy in the form of visible light. The varied colors observed in alkali metals result from the emission of light at specific wavelengths, dictated by the valence electrons' transition from higher to lower energy subshells during the de-excitation process.

Updated: Feb 28, 2024
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Alkali Metal Reactivity: Water, Chlorine, Oxygen, and Flame Tests. (2024, Feb 28). Retrieved from https://studymoose.com/document/alkali-metal-reactivity-water-chlorine-oxygen-and-flame-tests

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