Determining an Equilibrium constant

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To find out the equilibrium constant, Kc, for the reaction below, using acid hydrolysis: CH3COOC2H5 + H2O? CH3COOH + C2H5OH Theory although the hydolysis of ethyl ethanoate is very slow, by using dilute hydrochloric acid as catalyst which can be used to alter the time required to reach the equilibrium as the catalyst increases both the forward and backward reaction to the same extent,the above equilibrium can be attained in 48 hours. After 48 hours, the reaction mixture can then be titrated with standard sodium hydroxide solution.

Finally the equilibrium concentration of four components below and hence, Kc,, of hydrolysis of CH3COOC2H5 can then be calculated by the equilibrium law: Kc =image00. png The experiment can be divided into two parts: In part A: mixtures containing different proportions of the two reactants are added with a fixed amount of dilute hydrochloric acid as a catalyst. In part B: after the mixtures have reached equilibrium at room temperature, each one is titrated with sodium hydroxide.

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Controlled variables Independent variables Dependent variable Temperature.

Concentration of CH3COOC2H5 Concentration of NaOH volume of HCl added same electronic balance volume of CH3COOC2H5 added Volume of water added The volume of NaOH Safety Precautions Ethyl ethanoate –General Hazards Flammable Keep the liquid away from naked flame Keep the stopper on the bottle as much as possible Hydrochloric acid –General Hazards irritant wear gloves and safety googles Sodium hydroxide –General Hazards corrosive wear gloves and safety googles Special Handling Information Eye protection (safety goggles) must be worn at all times.

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Wear gloves Avoid skin contact with the chemicals Apparatus and Reagents Used (Part A) Safety spectacles 10 specimen tubes with well-fitting caps Labels for tubes and stoppers Access to a balance Pipette, 5 cm3, and safety filler Dilute hydrochloric acid, 2M HCl 2 measuring cylinders, 10 cm3 Distilled water Ethyl ethanoate, CH3COOC2H5 Procedures :( PART A) Ten specimen tubes were labeled with 1a, 1b, 1c, 1d, 2a, 2b, 3a, 3b, 4a, 4b. the stoppers were labeled too, so that they do not get misplaced. each tube is weight, with its stopper, and the masses are recorded in a copy of Results table 1.

A pipette and safety filler are used, 5 cm3 of 2Mhydrochloric acid is carefully added to each tube, the stoppers are replaced. Each stoppered tube is weight and the masses are recorded. A dry measuring cylinder is selected, and is used to add to tubes 2 the volumes of ethyl ethanoate shown in results table 1, the stoppers are replaced. The stoppered tubes 2Mass of water added /g Apparatus and Reagents Used (Part B) Safety spectacles 5 conical flasks,250 cm3 Wash-bottle of distilled water Phenolphthalein indicator Burette, stand and white tile Small funnel Sodium hydroxide solution,1M NaOH(standardised).

Procedures :(PART B) A burette is rinsed and filled with standardized sodium hydroxide solution. The contents of tube 1a into a conical flask. The tube is rinsed into the flask three times with distilled water. two to three drops of phenolphthalein indicator solution is added and the acid is titrated against sodium hydroxide solution. The burette reading is recorded in a copy of results table 2. image01. png steps 2 and 3 for each of the other tubes is repeated. image05. png Results Table 2 Solution in flask Equilibrium Mixture Solution in burette Sodium Hydroxide 0.970 mol dm-3 Indicator Tube Number 1constant, K 12 Mean Value of Kc image06. png Calculation :

( Set 2a) amount of acid: since HCl and NaOH react in equimolar amounts, so, amount of HCl added=concentration of NaOH X volume of NaOH added in1a =0. 970 X image07. png0. 0097mol Total amount of acid at equilibrium: =number of moles of HCl added+ CH3COOH formed =concentration of NaOH X volume of NaOH added in 2a =0. 970 X image08. png0. 0259mol equilibrium amount of ethanoic acid = Total amount of acid at equilibrium- amount of acid =(2)-(1) =0. 0162mol equilibrium amount of ethanol:= equilibrium amount of ethanoic acid =(3) =0. 0162mol.

Initial amount of ethyl ethanoate: image09. png =image10. png equilibrium amount of ethyl ethanoate = Initial amount of ethyl ethanoate- equilibrium amount of ethanoic acid =(5)-(4) =0. 0518-0. 0162 =0. 0356mol Mass of pure HCl: = amount of acid X molar mass of HCl =(1)X36. 5 =0. 354g Mass of water in HCl(aq) =mass of HCl added-mass of pure HCl =5. 15-0. 354 =4. 796g Initial amount of water =image11. png =image12. png equilibrium amount of water.

Initial amount of water- equilibrium amount of ethanoic acid =(9)-(3) =0. 2664-0.01615 =0. 2503mol equilibrium constant, Kc Kc =image00. png =image02. png Discussion on Errors Error: the weighting measurement of tubes may not be accurate due to the air current Impovement: close the window before measurement. Error: some deionized water used to rinse the test tubes may retain inside the bottles. By lechatelier’s principle, the increase in[H2O]promote the equilibrium shifts rightward. Improvement: allow some time to dry them Error: vaporization of CH3COOC2H5 will decrease [CH3COOC2H5] and hence affects Kc Improvement: the test tube should be sealed besides stopped.

Error: shake the test tubes too vigorously so that the mixture will be contaminated by the stoppers. Also if we shake it too vigorously, this will increase kinetic energy of chemicals and affects Kc Improvement: shake the test tubes gently. Error: the surrounding temperature is not constant thus this will alter Kc since Kc is temperature-dependent. Improvement: place the test tubes under electronic water bath. Error: Due to some measuring error, the amount of HCl is not the same so equilibrium amount of ethanoic acid obtained are not accurate which in turn affect Kc.

Improvement: use instrument with smaller graduation. Questions and answers By Le Chatelier’s principle, when a system at equilibrium is disturbed by a change in conditions (external factors), the equilibrium position shifts to the direction which tends to reduce the disturbance. Addiction of water, which in turn pushes the equilibrium shifting to the right so as to remove the additional water. Furthermore, one of the products is removed due to the neutralization of the equilibrium mixture with sodium hydroxide. The equilibrium position will shift rightward, producing more products so as to reduce more reactant.

Since the reaction is kinetically slow (even in the presence of the catalyst). The reaction is slow enough at room temperature so that the orders of mixing, temperature fluctuations over two days of reaction time, and even a final titration with a strong base have little effect on the reaction. It is possible to measure the ethanoic acid by titration with standard NaOH which remove ethanoic acid and catalyst hydrochloric acid without significantly disturbing the equilibrium position. Conclusion since equilibrium constant cannot be easily affected by physical factors, except for temperature.

Hence equilibrium of a reaction can be obtained by many methods, e. g. colorimetrical method. The one used in this experiment is titrimetric one since the hydrolysis is kinetically slow. By finding both equilibrium expression of products and reactants and follow the equation Kc =image00. png, equilibrium constant is found. Comments The value of equilibrium constant I obtained is 0. 027 which is much lower than the theoretical one-0. 25.

It is because the theoretical value of the equilibrium constant is calculated from standard conditions and therefore cannot be wholly compared with thevalue obtained from the room temperature and air pressure present in the laboratory. Since equilibrium constant is temperature-dependent.

This experiment is carried out under cold weather; the rate of reaction is slow, after 48 hours, less products are formed, total amount of acid at equilibrium decrease, in turn decrease in equilibrium amount of ethanoic acid thus Kc decrease. Besides low temperature, we also don’t shake it occasionally, after 48hours; the reaction may even not reach the equilibrium, so after calculation there is a large deviation with the theoretical one.

To find out whether the reaction reaches equilibrium of not after 48hours we can prepare one more tube during doing the experiment. Put the tube for 1 more week. Repeat the experiment again to see if there is more ethanoic acid produced. If so, the tubes used for calculation before have not reached the equilibrium.

There are five characteristics of a dynamic equilibrium Occurs in a closed system since the reaction above involves only liquids, no liquids can escape from the reaction mixture, it can be regarded as a closed system. equilibrium can be reached from either side since equilibrium only exist if the reaction is reversible, that means the equilibrium can also be reached by esterification between ethanol and ethanoic acid.

Chemical equilibrium are dynamic he forward reaction and backward reaction do not stop even if the equilibrium has been reached. The reactant particles keep on collide to give the product particles and the product keep on collide to give reactant particles. When the rate of the forward reaction is equal to that of the backward reaction, a state of dynamic equilibrium is reached. the microscopic processes continue, no overall macroscopic changes occur.

Change in conditions would result in a shift of equilibrium position temperature: depends on ? H of the reaction. Equilibrium shift to right, if the forward reaction is endothermic. Equilibrium shift to left, if the forward reaction is exothermic. Concentration: increase the concentration of reactants shifts the equilibrium position to the right. Increase the concentration of products shifts the equilibrium position to the left. Pressure: the increase in pressure does not affect the concentration of solid and liquid since the compressibility is rather low in solid and liquid state.

A catalyst does NOT affect the equilibrium position. A catalyst speeds up the rate of both the forward and reverse reactions. The initial slope of the concentration vs time lines will be steeper for both reactants and products. Reactants disappear faster while products are formed faster. At equilibrium the concentrations of reactants and products for the catalysed reaction are the same as for the uncatalysed reaction. image03. png The formation of ethyl ethanoate is particularly well-suited to the determination of the equilibrium constant.

Since there is a homogeneous reaction with the same number of moles of reactants and products, the equilibrium constant, Kc which generally expressed in terms of Molarity can be calculated in terms of moles alone and this add convenience. Since the equilibrium law expression of this reaction is independent of the volume. Ethanoic acid is a weak acid and therefore dissociates partially. The equilibrium is far to the right; this therefore means that the concentrations of the products of this reaction are assumed to be lower than they actually are. Modification of experiment: After calculating the equilibrium constant, we can determine H of the reaction.

Repeating the experiment of one set of data under different temperature, the corresponding equilibrium constant at certain temperature are calculated, then plot a graph lnK against 1/T image04. png By lnK = -? H/RT +C the slope =-? H/R by finding the slope we can find the? H too. Controlled variables Independent variables Dependent variable Concentration of CH3COOC2H5 Concentration of NaOH volume of HCl added volume of CH3COOC2H5 added Volume of water added same electronic balance temperature equilibrium constant.

Reference Textbook ( New Way Chemistry for Hong Kong A-level) Study guide Website ( ).

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Determining an Equilibrium constant. (2017, Sep 09). Retrieved from

Determining an Equilibrium constant

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